65128-79-2

Upstream product

• 21382-98-9 p-cyanophenyl methyl sulfide 
• 60958-06-7 4-Cyano-benzenesulfinyl chloride 
• 15898-42-7 sodium 4-cyanobenzenesulfinate 
• 49584-26-1 p-cyanobenzenesulfonyl chloride 
• 22821-76-7 4-(methylsulfonyl)benzonitrile 

Downstream Products

• 860700-93-2 4-((2-oxo-2-phenylethyl)sulfonyl)benzonitrile 
• 15898-42-7 sodium 4-cyanobenzenesulfinate 
• 137280-43-4 methyl p-cyanobenzenesulphinate 
• 438189-97-0 S-(4-cyanophenyl) 4-cyanobenzenesulfonothioate 

Relevant academic research and scientific papers

Tert-Butyl Nitrite Promoted Oxidative Intermolecular Sulfonamination of Alkynes to Synthesize Substituted Sulfonyl Pyrroles from the Alkynylamines and Sulfinic Acids

tert-Butyl nitrite promoted oxidative intermolecular sulfonamination of alkynes to synthesize substituted sulfonyl pyrroles from the alkynylamines and sulfinic acids via tandem addition/cyclization was developed. This reaction is performed well by employing tert-butyl nitrite as the oxidant, and various substituted sulfonyl pyrroles are formed in moderate to good yields with no requirement of metal catalysis.

Direct Irradiaton of Aryl Sulfides: Homolytic Fragmentation and Sensitized S-Oxidation

The direct irradiation of diphenyl sulfide and p-substituted thioanisoles in the presence of oxygen was investigated by means of both steady state and laser flash photolysis experiments. Two competitive pathways took place from the triplet excited state o

A General, One-Pot Method for the Synthesis of Sulfinic Acids from Methyl Sulfones

A simple and efficient method for converting methyl sulfones to sulfinic acids is described. The process involves alkylation with a benzylic halide, followed by in situ elimination of the resulting styrene in the presence of excess base to yield a sulfinic acid in a single reaction process. The usefulness of the alkylation-elimination sequence is demonstrated by generating a variety of sulfinic acids from methyl sulfones. Late stage functionalization and 14C-labeling of several biologically active methyl sulfones were accessed via sulfinate intermediates.

PHOTOINITIATORS HAVING TRIARYLSULFONIUM AND ARYLSULFINATE IONS

Compositions are provided that include a photoinitiator system for free radical polymerization reactions. More specifically, the photoinitiator includes an arylsulfinate ion and a triarylsulfonium ion. Polymerization methods are also provided those include the photoinitiator in a photopolymerizable composition. Additionally, triarylsulfonium arylsulfinate salts are disclosed.

DENTAL COMPOSITIONS AND METHODS WITH ARYLSULFINATE SALTS

Polymerizable compositions and methods are provided that include an ethylenically unsaturated compound and an arylsulfinate salt. The polymerizable compositions are useful as hardenable dental compositions.