65159-24-2

Basic information

• Product Name: 2,4-Bis(phenylimino)-3-pyrid-2-yl-pyrido<1,2-a>-1,3,5-triazin
• Synonyms: 2,4-Bis(phenylimino)-3-pyrid-2-yl-pyrido<1,2-a>-1,3,5-triazin
• CAS NO: 65159-24-2
• Molecular Weight: 390.447
• Mol File: 65159-24-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,4-Bis(phenylimino)-3-pyrid-2-yl-pyrido<1,2-a>-1,3,5-triazin(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-Bis(phenylimino)-3-pyrid-2-yl-pyrido<1,2-a>-1,3,5-triazin(65159-24-2)
• EPA Substance Registry System: 2,4-Bis(phenylimino)-3-pyrid-2-yl-pyrido<1,2-a>-1,3,5-triazin(65159-24-2)

Safety Data

• Hazardous Substances Data: 65159-24-2(Hazardous Substances Data)

Upstream product

• 88012-16-2 3-Phenyl-2-phenylimino-pyrido<1,2-a>-1,3,5-triazin-4-thion 
• 23574-81-4 N-(triphenylphosphoranylidene)pyridin-2-amine 
• 103-72-0 phenyl isothiocyanate 
• 103-71-9 phenyl isocyanate 

Relevant articles and documents

Reactions of Heteroaryliminotriphenylphosphoranes with Heterocumulenes: Synthesis and Cycloaddition Reactions of α-N-Heteroaryl-substituted Carbodiimides

N-α-Heteroaryl-substituted iminotriphenylphosphoranes react with phenylisocyanate, phenylisothiocyanate, and carbon disulfide to symmetrical and unsymmetrical α-heteroarylcarbodiimides.These can not be isolated as monomeres because they behave as 1.3-diazabutadienes predominantly and form 4+2-cycloadducts.The monomeric intermediates cyclodimerize to the 1.3.5-triazines 5 resp. 14 or react by the same scheme both with phenylisocyanate and with phenylisothiocyanate to give the 1.3.5-triazines 4, resp. 12.In competition with this reaction a 2+2-cycloaddition takes place, hence there follow numerous by-products.The structure of 1.3.5- triazines is determined from hydrolysis to guanidines 6 and on the basis of spectroscopic methods.