651719-15-2Relevant academic research and scientific papers
Ruthenium-Stabilized Low-Coordinate Phosphorus Atoms: Structural Evidence for Monomeric Metaphosphate
Menye-Biyogo, Richard,Delpech, Fabien,Castel, Annie,Gornitzka, Heinz,Riviere, Pierre
, p. 5610 - 5612 (2003)
Monomeric metaphosphonate is generated and stabilized within the coordination sphere of a ruthenium atom. The π system of a PO moiety coordinates to the transition metal center and this allows thermodynamic stabilization to give the first structural evidence for monomeric dioxophosphorane.
