651719-73-2Relevant academic research and scientific papers
Synthesis of Complex Tertiary Glycolates by Enantioconvergent Arylation of Stereochemically Labile α-Keto Esters
Bartlett, Samuel L.,Keiter, Kimberly M.,Johnson, Jeffrey S.
, p. 3911 - 3916 (2017/03/20)
Enantioconvergent arylation reactions of boronic acids and racemic β-stereogenic α-keto esters have been developed. The reactions are catalyzed by a chiral (diene)Rh(I) complex and provide a wide array of β-stereogenic tertiary aryl glycolate derivatives
1,5-Hydride shift in products of Stevens 3,2-rearrangement of methyl(alkyl)(alkoxycarbonylmethyl)-(3-phenyl-2- propynyl)ammonium bromides
Ovsepyan,Babakhanyan,Manukyan,Kocharyan
, p. 1376 - 1382 (2007/10/03)
The products of the Stevens 3,2-rearrangement of ammonium salts containing methyl and other (ethyl, propyl, butyl) alkyl groups along with 3-phenylprop-2-ynyl, under the reaction conditions undergo, roughly by half, intramolecular hydride shift with inter
Intramolecular 1,5-hydride shift in products of stevens 3,2-rearrangement of ammonium salts containing 3-phenyl-2-propynyl group
Babakhanyan,Ovsepyan,Kocharyan,Panosyan
, p. 814 - 819 (2007/10/03)
In products of Stevens 3,2-rearrangement of ammonium salts containing alongside alkoxycarbonylmethyl also 3-phenyl-2-propynyl group an intramolecular 1,5-hydride shift is observed resulting in immonium salts which transform into aminoesters of enamine str
