651768-64-8Relevant academic research and scientific papers
Aerobic oxidative amination of unactivated alkenes catalyzed by palladium
Brice, Jodie L.,Harang, Jenna E.,Timokhin, Vitaliy I.,Anastasi, Natia R.,Stahl, Shannon S.
, p. 2868 - 2869 (2005)
The first examples of palladium-catalyzed oxidative amination of unactivated alkyl olefins have been identified. To be successful, these reactions must be conducted under cocatalyst-free conditions that involve direct dioxygen-coupled turnover of the palladium catalyst. The oxidative amination products of norbornene and other cyclic alkenes implicate a cis-aminopalladation mechanism. Copyright
A Convenient Method for the Synthesis of α-Imidostyrenes from Styrenes and Imides via Diphenylstyrylsulfonium Salts
Yamanaka, Hiroyuki,Mukaiyama, Teruaki
, p. 1192 - 1193 (2007/10/03)
Styrenes having a hydrogen atom at the α-position reacted with diphenyl(trifluoromethanesulfonyloxy)sulfonium triflate (1) to form diphenylstyrylsulfonium triflates 2 that were in turn converted into the corresponding α-imidostyrenes on treatment with sodium or potassium salts of cyclic imides.
