65195-14-4

Usage

Uses

Used in Pharmaceutical Industry:
[1,1'-Biphenyl]-4-carbonyl chloride, 4'-propylis used as an intermediate in the synthesis of various pharmaceuticals due to its unique structure and reactivity. The presence of the carbonyl chloride group and the propyl chain at the 4' position allows for the creation of a diverse range of organic compounds with potential medicinal properties.
Used in Agrochemical Industry:
In the agrochemical industry, [1,1'-Biphenyl]-4-carbonyl chloride, 4'-propylis utilized as a building block for the development of new agrochemicals. Its chemical properties can be exploited to produce compounds with specific pesticidal, herbicidal, or fungicidal activities, contributing to the enhancement of crop protection and yield.
Used in Dye Industry:
[1,1'-Biphenyl]-4-carbonyl chloride, 4'-propylis also used in the dye industry as an intermediate for the production of various dyes. [1,1'-Biphenyl]-4-carbonyl chloride, 4'-propyl-'s structure can be modified to create dyes with specific color properties and stability, catering to the needs of different applications such as textiles, plastics, and printing inks.
Used in Organic Compounds and Materials Production:
[1,1'-Biphenyl]-4-carbonyl chloride, 4'-propylserves as a versatile intermediate in the production of a wide range of organic compounds and materials. The aliphatic chain and the carbonyl chloride group in [1,1'-Biphenyl]-4-carbonyl chloride, 4'-propylcan be used to synthesize compounds with tailored properties for specific applications in various industries, including plastics, coatings, and adhesives.

Upstream product

• 88038-94-2 4-(4-n-propylphenyl)benzoic acid 

Downstream Products

• 942231-08-5 (2S,4R)-4-hydroxy-4-(methoxymethyl)-1-(4'-propylbiphenylcarbonyl)-N-(tetrahydro-2H-pyran-2-yloxy)pyrrolidine-2-carboxamide 

Relevant academic research and scientific papers

Synthesis of aromatic liquid crystals with asymmetric diester based on rod-like multi-ring system by two-step esterification method

A novel method of two-step esterifications was developed to synthesize compounds with asymmetric double ester groups. By using this method, six rod-like double ester compounds were prepared with p-hydroxy benzaldehyde, p-hydroxy benzoic acid bicyclohexyl carboxylic acid, cyclohexyl benzoic acid and biphenyl carboxylic acid substituted by n-propyl and n-pentyl as main reactants. The structures and properties of target compounds were confirmed by IR, MS, 1H NMR, elemental analysis, differential scanning calorimetry (DSC) and hot stage polarizing optical microscope (HS-POM). Typical yields of the target molecules were more than 70%. All the molecules have mesophases with the textures of nematic type, indicating a rod-like molecule with a longer rigid skeleton can keep its mesophases. There was no clearing point observed for any of the derivatives before they decomposed so that the temperature ranges of the mesophases could not be determined. The energy differences between frontier molecular orbitals (HOMO-LUMO) (Eg) of the compounds were calculated by cyclic voltammetry (CV). The terminal ring system has an obvious influence on the energy levels and the energy gaps (Eg).

Liquid crystal of ethyl and propyl aromatic aldehyde with azo core and photosensitivity in mesophase

Eight new stable rod-like aromatic aldehyde liquid crystalline molecules with azo bridge have been prepared, in which single or double six-membered carbon ring carboxylic acid mesogenic cores with shorter alkyl chain of ethyl, n-propyl were condensed with hydroxyl azo benzaldehyde. These compounds have been characterized by their spectral data, DSC and HS-POM. These molecules were expected to exhibit liquid crystal phase so that the influence of UV-light on their textures of mesophase could be detected. The results showed that all these target compounds have the temperature range of mesophase between 101 and 145°C. After irradiating under UV-light, they exihibited photo-sensitivity not only in methanol but also in mesophase.

Synthesis of multiring azo-benzoic acid liquid crystalline molecules and their special photosensitive property

10 new rod-like azo benzoic acid liquid crystals belonged to three series have been prepared, in which trans-cyclohexyl benzene, biphenyl or bi-trans-cyclohexyl carboxylic acid mesogenic cores with ethyl, n-propyl, n-butyl or n-pentyl substituents were connected with azo benzoic acid. Meantime, a simple method was developed in synthesizing compounds bearing both ester and carboxyl groups in one-step reaction. All these compounds have been characterized on the basis of their spectral data, differential scanning calorimeter (DSC) and hot stage polarizing optical microscope (HS-POM). All these compounds have higher thermo-stability. 8 of these compounds have liquid crystalline properties. Their temperature ranges of mesophase have not been obtained, resulting from all the compounds decomposed before their clearing points. Although these compounds are photosensitive in solution under illumination of UV light (365nm), they can't do trans-cis isomerization in their mesophses, indicating the super stabilities of the trans isomer in mesophase.

Multirings aromatic aldehyde liquid crystal with azo linkage and their photosensitivity in mesophase

Ten new rod-like aromatic aldehyde liquid crystalline molecules with azo linkage were synthesized, in which bi(trans-cyclohexyl), cyclohexyl phenyl, and biphenyl carboxylic acid mesogenic cores with terminal ethyl, n-propyl, n-butyl, and n-pentyl substituents were esterified with azo benzoic aldehyde. These molecules were designed in an attempt to construct a series of new azo liquid crystalline molecules to investigate the influence of ultraviolet (UV) light on their mesophase. All compounds have been characterized on the basis of their spectral data, differential scanning calorimeter (DSC), and hot stage polarizing optical microscope (HS-POM). All these compounds exhibited liquid crystalline phase that belonged to nematic and photosensitive properties. Their temperature ranges of mesophase are from 101°C to 150°C. Under irradiated 365 nm UV light, they showed photosensitivity in the solvent of methanol. Observed under HS-POM, the UV light also did change the textures of these compounds. The result showed that terminal ethyl is enough for these molecules to exhibit wider temperature range of mesophase, and these new molecules have photosensitivities observed under illumination of UV light not only in solution but also in mesophase due to the change of their structures from trans isomer to cis one.

Tetraoxybiphenyl Ester Chiral Dopants for Cholesteric Liquid Crystal Displays

A liquid crystal composition comprising a chiral dopant compound represented by the following formula: wherein: R1, R2 are independently aryl, alkyl, alkenyl, cycloalkyl, alkoxyaryl, alkaryl or heterocyclic all either substituted or unsubstituted, or combine to form a carbocyclic or heterocyclic ring; R3 and R4 are independently hydrogen, halogen, cyano, alkoxy, NHCOR7, NHSO2R7, COOR7, OCOR7, aryl, alkyl, alkenyl, cycloalkyl, alkoxyaryl, alkaryl or heterocyclic all either substituted or unsubstituted, or combine with either R1 or R2 to form a carbocylic or heterocyclic ring; R5 and R6 are independently hydrogen, CH2, CH, alkyl or aryl either substituted or unsubstituted, COOR7, or combine with L to form a carbocyclic or heterocyclic ring; R7 is aryl, alkyl, alkenyl, cycloalkyl, alkoxyaryl or heterocyclic all either substituted or unsubstituted; L is the non-metallic elements required to form a carbocyclic or heterocyclic ring, or a single bond or a double bond; m is 1-3; n is 0-12.

N-HYDROXYAMIDE DERIVATIVES POSSESSING ANTIBACTERIAL ACTIVITY

Described herein are N-hydroxyamlde antibacterial compounds, methods for making the compounds, pharmaceutical compositions containing the compounds and methods of treating bacterial infections utilizing the compounds and pharmaceutical compositions compound of Formula (I): or a salt, solvate ti hydrate thereof, wherein A is (a) eachindicates a point of attachment.

BIPHENYLOXY-ACIDS

The present invention relates generally to substituted biphenyloxy acids (such as 4'-aryl-amido-biphenyl--4(3)-yloxy-acids and 4’-aryl-amidomethyl-biphenyl-4(3)-yloxy-acids) and methods of using them.

Synthesis and magnetic properties of some crystalline nitroxide radicals

The syntheses of different nitroxide radicals are reported. The thermal behaviour of the nitroxide radicals was examined by polarizing microscopy, differential scanning calorimetry as well as X-ray diffraction experiments. Temperature dependent magnetic susceptibility measurements were carried out in order to determine the magnetic properties of these nitroxide radicals. The majority of the radicals presented here show weak antiferromagnetic exchange interactions.

Novel liquid-crystalline and amorphous materials containing oxadiazole and amine moieties for electroluminescent devices

Three 1,3,4-oxadiazole derivatives with an amine and an alkyl tail were designed and synthesized as novel electroluminescent materials; it was found that the length of alkyl tail and the structure of the amine strongly affect the phase structure of the oxadiazole derivatives.