65202-12-2Relevant academic research and scientific papers
Standard Electrode Potential of Mercury-Mercurous Electrode at a Number of Temperatures
Choudhary, C. K.,Prasad, B.
, p. 555 - 557 (2007/10/02)
From the study of the cell; Pt Q.H.(sat.) HClO4 (c1) / HClO4 (c1 / HClO4 (c1), Hg2(ClO4) (c2) / Hg, the standard electrode potential of mercury-mercurous electrode has been determined from 5 deg C to 35 deg C at 5 deg C intervals.Over this range of temperatures the results can be expressed by the equation, Et = 0.80252 - 2.51 E-4 t - 1.0668 E-6 t2. ΔHO, ΔGO and ΔSO of the reaction Hg22+ + H2 = 2Hg + 2H+ have also been calculated.
