65220-26-0

Basic information

• Product Name: Benzene, 1-(1-azidoethenyl)-4-nitro-
• CAS NO: 65220-26-0
• Molecular Formula: C8H6N4O2
• Molecular Weight: 190.161
• Mol File: 65220-26-0.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(1-azidoethenyl)-4-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(1-azidoethenyl)-4-nitro-(65220-26-0)
• EPA Substance Registry System: Benzene, 1-(1-azidoethenyl)-4-nitro-(65220-26-0)

Safety Data

• Hazardous Substances Data: 65220-26-0(Hazardous Substances Data)

Upstream product

• 100-13-0 4-nitrostyrene 
• 21086-34-0 1,2-dibromo-1-(p-nitrophenyl)ethane 
• 937-31-5 (4-Nitrophenyl)acetylene 

Downstream Products

• 350-39-0 p-Nitro-α-fluoroacetophenone 

Relevant articles and documents

Electrocatalytic Synthesis of gem -Bisarylthio Enamines and α-Phenylthio Ketones via a Radical Process under Mild Conditions

The novel method for the synthesis of gem -bisarylthio enamines and α-phenylthio ketones was developed via the coupling of α-substituted vinyl azides with thiols in the presence of tetrabutylammonium iodide (TBAI) as a redox catalyst and electrolyte at ro

Access to Cycloalkeno[ c]-Fused Pyridines via Pd-Catalyzed C(sp2)-H Activation and Cyclization of N-Acetyl Hydrazones of Acylcycloalkenes with Vinyl Azides

A novel Pd(II)-catalyzed vinylic C-H activation and cyclization has been developed, reacting a series of small, medium, and large N-acetyl hydrazones of acylcycloalkenes with vinyl azides to access diverse cycloalkeno[c]-fused pyridine scaffolds. This protocol provides progress in C(sp2)-H bond activation of medium to large cycloalkenes, and the target products can be obtained in a specific regioselectivity with good functional group tolerance and a broad substrate scope.

Highly Enantioselective Iridium-Catalyzed Coupling Reaction of Vinyl Azides and Racemic Allylic Carbonates

The iridium-catalyzed enantioselective coupling reaction of vinyl azides and allylic electrophiles is presented and provides access to β-chiral carbonyl derivatives. Vinyl azides are used as acetamide enolate or acetonitrile carbanion surrogates, leading to γ,δ-unsaturated β-substituted amides as well as nitriles with excellent enantiomeric excess. These products are readily transformed into chiral N-containing building blocks and pharmaceuticals. A mechanism is proposed to rationalize the chemoselectivity of this coupling reaction.