6523-29-1 Usage
Molecular structure
Heterocyclic organic compound with a bicyclic structure and a nitrogen atom at the bridgehead position
Functional groups
Two nitrogen atoms in the ring structure
Physical state
Solid at room temperature
Solubility
Soluble in water and many organic solvents
Uses
a. Catalyst in organic synthesis for various reactions
b. Synthesis of pharmaceuticals, polymers, and other organic compounds
c. Production of polyurethane foams and coatings
d. Formulation of adhesives and sealants
e. Development of novel functional materials in materials science
Chemical properties
a. Strong and versatile base
b. Promotes various chemical reactions
c. Ability to act as a catalyst in organic chemistry
Safety
a. May cause eye, skin, and respiratory irritation
b. Avoid contact with eyes, skin, and ingestion
c. Use appropriate personal protective equipment (PPE) when handling
Storage
Store in a cool, dry, and well-ventilated area, away from incompatible substances and sources of ignition.
Check Digit Verification of cas no
The CAS Registry Mumber 6523-29-1 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,5,2 and 3 respectively; the second part has 2 digits, 2 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 6523-29:
(6*6)+(5*5)+(4*2)+(3*3)+(2*2)+(1*9)=91
91 % 10 = 1
So 6523-29-1 is a valid CAS Registry Number.
InChI:InChI=1/C7H14N2/c1-8-6-7-2-4-9(8)5-3-7/h7H,2-6H2,1H3
6523-29-1Relevant articles and documents
Electron Transfer in the Decomposition of Hexaalkylhydrazine Dications
Nelsen, Stephen F.,Ippoliti, J. Thomas
, p. 3169 - 3176 (1986)
Rearrangements of hexaalkylhydrazine dications +N+R3> to α-amino ammonium cations +CHR'NR2> derived by Hofman-like degradation (loss of an α proton and NN bond cleavage to give an amino immonium cation, followed by addition of the amino group to the C=N+ bond) are investigated.Tricyclic dications 62+ and 102+ give 14+ and 8+, respectively, showing high selectivity for hydrogen loss from the methylenes in the bicyclooctyl rings which can have CH bonds aligned with the NN bond over the three other types of methylene groups as well as the methyl group.Selectivity for hydrogen loss from the methyl and methylene carbons of the bicyclic cations 32+ proves to be sensitive to the reaction conditions.NCH3/NCH2 attack ratios from 4 to 10 were observed for carbonate and chloride in acetonitrile (chloride in water failed to react), but a ratio of about 1 was observed for iodide in both acetonitrile and water.It is argued that iodide decomposes the dications by an electron-transfer mechanism in which the key step is hydrogen atom abstraction from the 3e-?-bonded cation radical.This is consistent with the observed even higher selectivity to HC,NN bond alignment than occurs for base attack on the dication.
