65240-71-3Relevant academic research and scientific papers
Utilization of natural sunlight and air in the aerobic oxidation of benzyl halides
Su, Yijin,Zhang, Liangren,Jiao, Ning
supporting information; body text, p. 2168 - 2171 (2011/06/21)
Chemical equations presented. A novel, efficient oxidation of α-aryl halogen derivatives to the corresponding α-aryl carbonyl compounds at room temperature has been disclosed. Natural sunlight and air are successfully utilized in this approach through the combination of photocatalysis and organocatalysis. A plausible mechanism was proposed on the basis of the mechanistic studies.
"STRUCTURE-REACTIVITY-SELECTIVITY" RELATIONSHIP IN SN2 PROCESSES. REACTION OF 4,4'-SUBSTITUTED α-CHLORODEOXYBENZOINS WITH SODIUM THIOPHENOLATES
Karavan, V. S.,Simonov, D. A.
, p. 145 - 148 (2007/10/02)
In the SN2 reactions of α-chlorodeoxybenzoins X'C6H4CHClCOC6H4X with YC6H4SNa in methanol there is no unambiguous relationship at all between the reactivity of the substrate and its selectivity toward the nucleophile (ρY).At the same
