65248-51-3

Upstream product

• 79-30-1 isobutyryl chloride 
• 2687-12-9 cinnamyl chloride 
• 2046-18-6 4-phenylbutyronitrile 
• 14252-46-1 2,2-bis(phenylthio)propane 

Relevant academic research and scientific papers

Titanocene(II)-promoted desulfurizative acylation of thioacetals with alkanenitriles

Ketones were obtained in good yields by titanocene(II)-promoted reaction of thioacetals with alkanenitriles. The regioselective formation of α-substituted ketone was observed when the reaction was carried out in the presence of methyl iodide or benzyl bro

Transition-Metal-Free Homologative Cross-Coupling of Aldehydes and Ketones with Geminal Bis(boron) Compounds

We report a transition-metal-free coupling of aldehydes and ketones with geminal bis(boron) building blocks which provides the coupled, homologated carbonyl compound upon oxidation. This reaction not only extends an alkyl chain containing a carbonyl group, it also simultaneously introduces a new carbonyl substituent. We demonstrate that enantiopure aldehydes with an enolizable stereogenic center undergo this reaction with complete retention of stereochemistry.