65253-43-2Relevant academic research and scientific papers
Some Studies on the Reversibility of the Association Step in SRN1 Reactions
Norris, Robert K.,Wright, Timothy A.
, p. 1107 - 1116 (2007/10/02)
The association step in SRN1 reactions, in which p-nitrobenzylic radicals are trapped by aci-nitronate ions or the anions from β-keto esters, is demonstrated to be effectively irreversible under the normal conditions of the SRN1 reac
Regiochemistry of the Association Step in SRN1 Reactions; Kinetically Controlled Coupling of aci-Nitronate Ions and p-Nitrobenzylic Radicals
Norris, Robert K.,Randles, David
, p. 1047 - 1051 (2007/10/02)
The regiochemistry of the coupling between p-nitrobenzylic radicals and aci-nitronate ions in the association step of SRN1 reactions is shown to be dependent on steric factors.Branching at the carbon which is α to the reaction site causes a shi
