65263-87-8Relevant academic research and scientific papers
Interconversion of γ-Silyl α,β-Unsaturated Carbonyl Compounds and Siloxybutadienes by 1,5-Shifts of Silicon between Carbon and Oxygen
Casey, Charles P.,Jones, Carol R.,Tukada, Hideyuki
, p. 2089 - 2092 (1981)
Reaction of lithium biscuprate (1) with (E)-4-chloro-3-penten-2-one (2-E) gives (E)-4-methyl-5-(trimethylsilyl)-3-penten-2-one (3-E).Photolysis of 3-E at low temperature gives a 56:44 mixture of 3-E and 3-Z.Upon being warmed to 34
