65288-07-5Relevant academic research and scientific papers
Experimental evidence for negative hyperconjugation as a component of the polar effect: Variation of the ease of α-sulfonyl carbanion formation with the orientation of a β-alkoxy substituent
King, James F.,Rathore, Rajendra,Guo, Zhenrong,Li, Manqing,Payne, Nicholas C.
, p. 10308 - 10324 (2000)
We report evidence for a strongly geometry-dependent substituent effect. The rate constants for H-D exchange of the α-hydrogens, (k(exch))OR, in a set of 19 β-alkoxy sulfones of known, fixed (or strongly preferred) H-C(α)-C(β)-OR torsion angles have been
Lipase-mediated diastereoselective and enantioselective acetylations of 3-substituted cyclohexanols
Tanikaga, Rikuhei,Morita, Akira
, p. 635 - 638 (2007/10/03)
Lipase-mediated acetylation of four diastereomeric and enantiomeric isomers of 3-substituted cyclohexanols 2 has led to an efficient resolution to provide a single stereoisomer, (1R,3S)-cyclohexyl acetate (1R,3S)-3 in a high enantiomeric excess.
