65293-32-5Relevant academic research and scientific papers
Synthesis of β-glycosyl formamides through N-glycosylation of unprotected carbohydrates
Ichikawa, Yoshiyasu,Matsukawa, Akihito,Maeda, Mitsutoshi,Tomita, Yumiko,Mimura, Rika,Kitamori, Ayumi,Kotsuki, Hiyoshizo,Nakano, Keiji,Masuda, Toshiya
, p. 2201 - 2212 (2017/02/10)
Two new synthetic routes involving N-glycosylation of unprotected carbohydrates were developed for the preparation of β-glycosyl formamides. Using this protocol, D-glucose, D-xylose, D-galactose and D-maltose were transformed to their corresponding β-glyc
The structure of glycosyl amides: A combined study by NMR spectroscopy, X-ray crystallography, and computational chemistry
Avalos, Martin,Babiano, Reyes,Carretero, Maria J.,Cintas, Pedro,Higes, Francisco J.,Jimenez, Jose L.,Palacios, Juan C.
, p. 615 - 628 (2007/10/03)
The structure of N-formyl, N-acetyl-N-methyl, and N-acetyl glycosylamines has been studied by NMR spectroscopy in solution, single crystal X-ray diffractometry, and corroborated by PM3 semiempirical calculations. The results quite agree with an anti con formation around the glycosydic bond for these substances.
