65332-44-7Relevant academic research and scientific papers
Visible-light C-heteroatom bond cleavage and detoxification of chemical warfare agents using titania-supported gold nanoparticles as photocatalyst
Neau, Tefan,Cojocaru, Bogdan,Parvulescu, Vasile I.,Omoghi, Vasile,Alvaro, Mercedes,Garcia, Hermenegildo
supporting information; scheme or table, p. 4050 - 4054 (2011/07/29)
Gold nanoparticles supported on TiO2 effect the detoxification of soman and VX nerve gases and yperite vesicant agent at room temperature upon visible light illumination.
Analysis of chemical neutralization products of phosphonothiolates by gas chromatography mass spectrometry
Gupta,Palit,Dubey,Raza
, p. 1631 - 1637 (2007/10/03)
A series of phosphonothiolates, including the highly toxic O-Ethyl-S-(2-diisopropylamino) ethyl methylphosphonothioate (VX), have been subjected to chemical neutralization reaction with metallic sodium. The phosphonothiolates decompose to their respective phosphonic and phosphonothioic acids and this results in the detoxification of VX. GC/MS technique in both EI and CI mode has been applied for reaction monitoring and final identification of the neutralization products formed in this reaction.
&β-(N,N-Dialkylamino)ethyl Arylthiosulfonates: New Simulants for O-Ethyl S- Methylphosphonothioate
Davis, Franklin A.,Ray, Jayanta K.,Kasperowicz, Steve,Przeslawski, Robert M.,Durst, H. Dupont
, p. 2594 - 2599 (2007/10/02)
β-(N,N-Dialkylamino)ethyl arylthiosulfonates 2, new simulants for the hydrolysis and oxidation chemistry of VX (1), are prepared in good yield by reaction of a potassium arylthiosulfonate with a 2-chloroethylamine.Alkaline hydrolysis of 2 results in cleavage of the S-S-bond to give sulfinic acids and disulfides.Like VX, oxidation of 2 by N-sulfonyloxaziridine 12 occurs exclusively on nitrogen to give the corresponding amine oxide which subsequently undergoes a Cope elimination reaction affording the vinyl sulfide 14.
