65335-72-0

Basic information

• Product Name: Silane, [(1-ethyl-1-propenyl)oxy]dimethylphenyl-
• CAS NO: 65335-72-0
• Molecular Formula: C13H20OSi
• Molecular Weight: 220.387
• Mol File: 65335-72-0.mol

Chemical Properties

• CAS DataBase Reference: Silane, [(1-ethyl-1-propenyl)oxy]dimethylphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, [(1-ethyl-1-propenyl)oxy]dimethylphenyl-(65335-72-0)
• EPA Substance Registry System: Silane, [(1-ethyl-1-propenyl)oxy]dimethylphenyl-(65335-72-0)

Safety Data

• Hazardous Substances Data: 65335-72-0(Hazardous Substances Data)

Upstream product

• 766-77-8 Dimethylphenylsilane 
• 96-22-0 pentan-3-one 

Downstream Products

• 104108-06-7 (4S,5R)-5-(Dimethyl-phenyl-silanyloxy)-4-methyl-7-phenyl-heptan-3-one 
• 104108-06-7 (4R,5R)-5-(Dimethyl-phenyl-silanyloxy)-4-methyl-7-phenyl-heptan-3-one 
• 134810-63-2 1-(Dimethyl-phenyl-silanyloxy)-2-methyl-1-phenyl-pentan-3-one 
• 104108-04-5 (1R,2S)-1-(Dimethyl-phenyl-silanyloxy)-2-methyl-1-phenyl-pentan-3-one 
• 104108-04-5 (1R,2R)-1-(Dimethyl-phenyl-silanyloxy)-2-methyl-1-phenyl-pentan-3-one 
• 107995-04-0 (Z)-(4S,5S)-7-(Dimethyl-phenyl-silanyloxy)-4,5-dimethyl-7-phenyl-hept-6-en-3-one 
• 107995-04-0 (Z)-(4R,5S)-7-(Dimethyl-phenyl-silanyloxy)-4,5-dimethyl-7-phenyl-hept-6-en-3-one 

Relevant articles and documents

Base-free dehydrogenative coupling of enolizable carbonyl compounds with silanes

A dehydrogenative coupling between enolizable carbonyl compounds and equimolar amounts of triorganosilanes catalyzed by a tethered ruthenium complex with a Ru-S bond is reported. The complex is assumed to fulfill a dual role by activating the Si-H bond to release a silicon electrophile and by abstracting an α-proton from the intermediate silylcarboxonium ion, only liberating dihydrogen as the sole byproduct. Reaction rates are exceedingly high at room temperature with very low loadings of the ruthenium catalyst.