65372-01-2

Basic information

• Product Name: 2-methyl-(4-O-acetyl-3,6-di-O-benzyl-1,2-dideoxy-α-D-glucopyrano)-<2,1-d>-2-oxazoline
• Synonyms: 2-methyl-(4-O-acetyl-3,6-di-O-benzyl-1,2-dideoxy-α-D-glucopyrano)-<2,1-d>-2-oxazoline
• CAS NO: 65372-01-2
• Molecular Weight: 425.481
• Mol File: 65372-01-2.mol

Chemical Properties

• CAS DataBase Reference: 2-methyl-(4-O-acetyl-3,6-di-O-benzyl-1,2-dideoxy-α-D-glucopyrano)-<2,1-d>-2-oxazoline(CAS DataBase Reference)
• NIST Chemistry Reference: 2-methyl-(4-O-acetyl-3,6-di-O-benzyl-1,2-dideoxy-α-D-glucopyrano)-<2,1-d>-2-oxazoline(65372-01-2)
• EPA Substance Registry System: 2-methyl-(4-O-acetyl-3,6-di-O-benzyl-1,2-dideoxy-α-D-glucopyrano)-<2,1-d>-2-oxazoline(65372-01-2)

Safety Data

• Hazardous Substances Data: 65372-01-2(Hazardous Substances Data)

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 65947-37-7 allyl 2-deoxy-2-acetamido-4,6-O-benzylidene-β-D-glucopyranoside 
• 65947-38-8 N-((4aR,6R,7R,8R,8aS)-6-Allyloxy-8-benzyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl)-acetamide 
• 3006-60-8 2-acetamido-3,4,6-tri-O-acetyl-D-glucopyranosyl acetate 
• 63064-48-2 allyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-β-D-glucopyranoside 
• 54400-75-8 allyl 2-acetamido-2-deoxy-β-D-glucopyranoside 
• 65730-05-4 1-propenyl 2-acetamido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside 
• 74653-17-1 allyl 2-acetamido-2-deoxy-4-O-(tetrahydropyran-2-yl)-β-D-glucopyranoside 
• 74948-66-6 allyl 2-acetamido-3,6-di-O-benzoyl-2-deoxy-4-O-(2-tetrahydropyranyl)-β-D-glucopyranoside 
• 74948-67-7 allyl 2-acetamido-3,6-di-O-benzyl-2-deoxy-4-O-(2-tetrahydropyranyl)-β-D-glucopyranoside 
• 65730-02-1 allyl 2-acetamido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside 
• 70834-40-1 allyl 2-acetamido-3,6-di-O-benzoyl-2-deoxy-β-D-glucopyranoside 
• 65371-99-5 1-propenyl 2-acetamido-4-O-acetyl-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside 
• 65371-99-5 Acetic acid (2R,3S,4R,5R,6R)-5-acetylamino-4-benzyloxy-2-benzyloxymethyl-6-[((E)-propenyl)oxy]-tetrahydro-pyran-3-yl ester 

Downstream Products

• 115491-86-6 Sodium; 2-{[(2S,4S)-4-((2R,3R,4R,5S,6R)-3-acetylamino-4-benzyloxy-6-benzyloxymethyl-5-sulfooxy-tetrahydro-pyran-2-yloxy)-1-benzyloxycarbonyl-pyrrolidine-2-carbonyl]-amino}-ethanesulfonate 
• 115516-58-0 (2S,4S)-4-((2R,3R,4R,5S,6R)-3-Acetylamino-4-benzyloxy-6-benzyloxymethyl-5-sulfooxy-tetrahydro-pyran-2-yloxy)-pyrrolidine-1,2-dicarboxylic acid 1-benzyl ester 2-(2,5-dioxo-pyrrolidin-1-yl) ester; compound with triethyl-amine 
• 115516-56-8 (2S,4S)-4-((2R,3R,4R,5S,6R)-3-Acetylamino-4-benzyloxy-6-benzyloxymethyl-5-hydroxy-tetrahydro-pyran-2-yloxy)-pyrrolidine-1,2-dicarboxylic acid 1-benzyl ester 2-(2,5-dioxo-pyrrolidin-1-yl) ester 
• 78139-21-6 allyl O-(2-acetamido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranosyl)-(1->4)-2-acetamido-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside 
• 78139-18-1 benzyl 4-O-(2-acetamido-4-O-acetyl-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranosyl)-2,3,6-tri-O-benzyl-1-thio-β-D-galactopyranoside 
• 72894-34-9 benzyl 6-O-(2-acetamido-4-O-acetyl-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-1-thio-β-D-galactopyranoside 
• 74653-20-6 allyl 2-acetamido-4-O-(2-acetamido-4-O-acetyl-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranosyl)-3,6-di-O-(2-butenyl)-2-deoxy-β-D-glucopyranoside 
• 115491-85-5 (2S,4S)-4-((2R,3R,4R,5S,6R)-5-Acetoxy-3-acetylamino-4-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-pyrrolidine-1,2-dicarboxylic acid 1-benzyl ester 2-methyl ester 
• 78139-20-5 allyl 2-acetamido-4-O-(2-acetamido-4-O-acetyl-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranosyl)-3,6-di-O-benzyl-2-deoxy-β-D-glucopyranoside 

Relevant articles and documents

Iodine as a Reagent for the Ready Hydrolysis of Prop-1-enyl Glycosides, or their Conversion into Oxazolines

Iodine in oxolan with suitable additives rapidly effects the hydrolysis of prop-1-enyl glycosides to free sugars, and the cyclization of prop-1-enyl β-glycosides of N-acylglucosamines to oxazolines.

O-BENZYLATED OXAZOLINE DERIVATIVES OF 2-ACETAMIDO-2-DEOXY-D-GLUCOPYRANOSE FROM 1-PROPENYL GLYCOSIDES. SYNTHESIS OF THE PROPENYL GLYCOSIDES AND THEIR DIRECT CYCLIZATION

1-Propenyl 2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-α- and -β-D-glucopyranosides (3α, 3β) were obtained by the successive isomerization and acetylation of the known allyl glycosides 1α and 1β.The allyl glycosides were also converted, via their benzylidene 4