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65476-99-5

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65476-99-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 65476-99-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,5,4,7 and 6 respectively; the second part has 2 digits, 9 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 65476-99:
(7*6)+(6*5)+(5*4)+(4*7)+(3*6)+(2*9)+(1*9)=165
165 % 10 = 5
So 65476-99-5 is a valid CAS Registry Number.

65476-99-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-methyl-4-phenyl-1-butylamine

1.2 Other means of identification

Product number -
Other names 2-methyl-4-phenylbutylamine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:65476-99-5 SDS

65476-99-5Downstream Products

65476-99-5Relevant articles and documents

Fast Titanium-Catalyzed Hydroaminomethylation of Alkenes and the Formal Conversion of Methylamine

Bielefeld, Jens,Doye, Sven

supporting information, p. 6138 - 6143 (2020/03/13)

The scientific interest in catalytic hydroaminoalkylation reactions of alkenes has vastly increased over the past decade, but these reactions have struggled to become a viable option for general laboratory or industrial use because of reaction times of several days. The titanium-based catalytic system introduced in this work not only reduces the reaction time by several orders of magnitude, into the range of minutes, but the catalyst is also demonstrated to be easily available from common starting materials, at a cost of approximately 1 € per millimole of catalyst. We were also able to formally perform C?H activation of methylamine and achieve coupling to a broad variety of alkenes, through silyl protection of the amine and simple deprotection by water.

An Iodine-Catalyzed Hofmann-L?ffler Reaction

Martínez, Claudio,Mu?iz, Kilian

supporting information, p. 8287 - 8291 (2015/07/07)

Iodine reagents have been identified as economically and ecologically benign alternatives to transition metals, although their application as molecular catalysts in challenging C-H oxidation reactions has remained elusive. An attractive iodine oxidation catalysis is now shown to promote the convenient conversion of carbon-hydrogen bonds into carbon-nitrogen bonds with unprecedented complete selectivity. The reaction proceeds by two interlocked catalytic cycles comprising a radical chain reaction, which is initiated by visible light as energy source. This unorthodox synthetic strategy for the direct oxidative amination of alkyl groups has no biosynthetic precedence and provides an efficient and straightforward access to a general class of saturated nitrogenated heterocycles.

Model Studies of the Reduction of 3-Phenyl-6H-1,2-oxazines, Chemo- and Stereoselectivity: Synthesis of Amino Alcohols, Amino Acids, and Related Compounds

Zimmer, Reinhold,Hoffmann, Matthias,Reissig, Hans-Ulrich

, p. 2243 - 2248 (2007/10/02)

While palladium-catalyzed hydrogenation of 3-phenyl-6H-1,2-oxazine 1 produces primary amine 5 in a nitrogen-transposition reaction, the reductions of the related 1,2-oxazines 2, 10, and the 1,2-oxazin-6-one 3 afford the expected amino alcohols 4, 11, and the γ-amino acid 6, respectively, with low diastereoselectivities.In the presence of acetic acid 3 is reductively converted into γ-keto carboxylic acid 9 and 1 into the γ-lactam derivative 12 probably by a ring contraction to a nitrone intermediate.Raney nickel as the catalyst is able to transform 1,2-oxazine 7 bearing an exo-methylene unit into 3,4-dihydro-2H-pyrrole 13.The reaction of 6H-1,2-oxazine 1 with aluminium amalgam produces pyrrole 14 in moderate yield.Treatment of 1 with sodium in 2-propanol brings about its transformation into pyrrolidine derivative 15 together with pyrrole 14 and amino alcohol 4 as minor products.The chemoselectivity and stereoselectivity of these reductions are discussed including mechanistic proposals for the multistep processes involved. Key Words: 1,2-Oxazines / Hydrogenation, catalytic / Amino alcohols / γ-Amino acids / Pyrroles / γ-Lactams

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