65514-51-4

Basic information

• Product Name: hydridoaluminum(2+) bis(2,2-dimethylpropan-1-ide)
• CAS NO: 65514-51-4
• Molecular Formula: C₂₀H₄₆Al₂
• Molecular Weight: 170.2712
• Mol File: 65514-51-4.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 7.2°C at 760 mmHg
• Vapor Pressure: 1420mmHg at 25°C
• CAS DataBase Reference: hydridoaluminum(2+) bis(2,2-dimethylpropan-1-ide)(CAS DataBase Reference)
• NIST Chemistry Reference: hydridoaluminum(2+) bis(2,2-dimethylpropan-1-ide)(65514-51-4)
• EPA Substance Registry System: hydridoaluminum(2+) bis(2,2-dimethylpropan-1-ide)(65514-51-4)

Safety Data

• Hazardous Substances Data: 65514-51-4(Hazardous Substances Data)

Upstream product

• 42916-36-9 tris(neopentyl)aluminium 
• 16853-85-3 lithium aluminium tetrahydride 

Downstream Products

• 1565836-62-5 C₄₆H₇₃Al₂P 
• 1565836-64-7 C₄₀H₆₁Al₂P 
• 1308317-95-4 HC(C(CH₃)3)CP(C₆H₂(CH₃)3)2Al(CH₂C(CH₃)3)2 
• 1239866-51-3 (C₆H₅)2Ge(CCC₆H₅)[C(Al(CH₂C(CH₃)3)2)C(H)C₆H₅] 
• 1239590-73-8 (dimethyl)(phenylethinyl)(silicon)C(CHC₆H₅)bis(neopentyl)aluminum 
• 1239590-81-8 (phenylethinyl)(CH₂)3(silicon)C(CHC₆H₅)(bis(neopentyl)aluminum) 
• 1214751-26-4 (((CH₃)3CCH₂)2Al(CCC(CH₃)3))2 
• 110638-24-9 dineopentylaluminum{Ph₂phosphide} 

Relevant articles and documents

Group 13-derived radicals from α-diimines: Via hydro-and carboalumination reactions

The mechanochemical synthesis of tertiary and secondary alanes AlR3 (R = Np 1 or Mes 2; HAlR2 R = Np 3 or Mes 4) is described. These species are reacted with several α-diimines to give a series of aluminium-derived radicals of the form [(diimine)AlR2] (6-11). EPR and several crystallographic studies are reported. These species are thought to form via hydro-or carboalumination and subsequent elimination reactions. This view is supported by the structural data for minor products C12H7(NHDipp)(NDipp)AliBu25 and C13H8(C(iBu)N(m-Xy)(NH(m-Xy)))AliBu212. In addition, the characterization of (C6F5)2B(OC(C6F5)OC12H8) indicates that such a carboboration pathway also provides access to related boron-derived radicals.