65514-51-4

Upstream product

• 16853-85-3 lithium aluminium tetrahydride 
• 42916-36-9 tris(neopentyl)aluminium 

Downstream Products

• 110638-24-9 dineopentylaluminum{Ph₂phosphide} 
• 1239866-51-3 (C₆H₅)2Ge(CCC₆H₅)[C(Al(CH₂C(CH₃)3)2)C(H)C₆H₅] 
• 1308317-95-4 HC(C(CH₃)3)CP(C₆H₂(CH₃)3)2Al(CH₂C(CH₃)3)2 
• 1565836-64-7 C₄₀H₆₁Al₂P 
• 1565836-62-5 C₄₆H₇₃Al₂P 
• 1239590-73-8 (dimethyl)(phenylethinyl)(silicon)C(CHC₆H₅)bis(neopentyl)aluminum 
• 1239590-81-8 (phenylethinyl)(CH₂)3(silicon)C(CHC₆H₅)(bis(neopentyl)aluminum) 
• 1214751-26-4 (((CH₃)3CCH₂)2Al(CCC(CH₃)3))2 

Relevant academic research and scientific papers

Group 13-derived radicals from α-diimines: Via hydro-and carboalumination reactions

The mechanochemical synthesis of tertiary and secondary alanes AlR3 (R = Np 1 or Mes 2; HAlR2 R = Np 3 or Mes 4) is described. These species are reacted with several α-diimines to give a series of aluminium-derived radicals of the form [(diimine)AlR2] (6-11). EPR and several crystallographic studies are reported. These species are thought to form via hydro-or carboalumination and subsequent elimination reactions. This view is supported by the structural data for minor products C12H7(NHDipp)(NDipp)AliBu25 and C13H8(C(iBu)N(m-Xy)(NH(m-Xy)))AliBu212. In addition, the characterization of (C6F5)2B(OC(C6F5)OC12H8) indicates that such a carboboration pathway also provides access to related boron-derived radicals.

Synthesis and characterization of neopentylaluminum compounds

The series of neopentylaluminum compounds, Al(CH2CMe3)3, Al(CH2CMe3)2H, Al(CH2CMe3)2Br, (Me3CCH2)2AlPPh2, and (Me3CCH2)2AlN(Me)H, have been prepared by reactions typical in organoaluminum chemistry and characterized by elemental and/or group analysis, cryoscopic molecular weight measurements in benzene solution, and IR and NMR spectroscopic data. All compounds in this series, except Al(CH2CMe3)3, are associated in benzene solution. Even though the neopentyl group is considered a bulky ligand with significant eteric effects, the Lewis acidity of Al(CH2CMe3)3 has been established by the formation and characterization of adducts LiAl(CH2CMe3)4, (Me3CCH2)3Al·PPh2H, and (Me3CCH2)3Al·N(Me)H2. However, since Al(CH2CMe3)3 is monomeric in benzene solution, the factors influencing the degree of association of organoaluminum compounds are discussed. The crystalline hydride Al(CH2CMe3)2H has been prepared from Al(CH2CMe3)3 and LiAlH4. The other product was LiH rather than LiAl(CH2CMe3)H3. These observations of products are unusual in organoaluminum chemistry.