65536-89-2Relevant academic research and scientific papers
Hydroxoiridium-Catalyzed Hydroalkylation of Terminal Alkenes with Ureas by C(sp3)?H Bond Activation
Yamauchi, Daisuke,Nishimura, Takahiro,Yorimitsu, Hideki
supporting information, p. 7200 - 7204 (2017/06/13)
Direct alkylation of a methyl group, on di- and trisubstituted ureas, with terminal alkenes by C(sp3)?H bond activation proceeded in the presence of a hydroxoiridium/bisphosphine catalyst to give high yields of the corresponding addition products. The hydroxoiridium/bisphosphine complex generates an amidoiridium intermediate by reaction with ureas having an N?H bond.
