65538-07-0Relevant academic research and scientific papers
α,ω-PERFLUOROALKYLENEBIS(ARYLIODONIUMS)
Mironova, A. A.,Maletina, I. I.,Orda, V. V.,Yagupol'skii, L. M.
, p. 1082 - 1085 (2007/10/02)
α,ω-Bisperfluoroalkanes have been obtained by oxidizing α,ω-diiodoperfluoroalkanes with trifluoroperacetic acid.With the aid of sulfur tetrafluoride, they have been converted into α,ω-bis(difluoroiodo)perfluoroalkanes.Upon condensation with benzene in the presence of boron trifluoride, the latter form α,ω-perfluoroalkylenebis(phenyliodonium) fluoroborates, which are new reagents for the synthesis of bifunctional derivatives of perfluoroalkanes.The reaction of α,ω-bisperfluoroalkanes with benzene and toluene has yielded α,ω-perfluoroalkylenebis(aryliodonium) trifluoroacetates.
