65548-56-3Relevant academic research and scientific papers
Toward a Unified Mechanism for Oxoammonium Salt-Mediated Oxidation Reactions: A Theoretical and Experimental Study Using a Hydride Transfer Model
Hamlin, Trevor A.,Kelly, Christopher B.,Ovian, John M.,Wiles, Rebecca J.,Tilley, Leon J.,Leadbeater, Nicholas E.
, p. 8150 - 8167 (2015/09/02)
A range of oxoammonium salt-based oxidation reactions have been explored computationally using density functional theory (DFT), and the results have been correlated with experimentally derived trends in reactivity. Mechanistically, most reactions involve a formal hydride transfer from an activated C-H bond to the oxygen atom of the oxoammonium cation. Several new potential modes of reactivity have been uncovered and validated experimentally.
