65609-73-6

Basic information

• Product Name: N′-(4-tert-butylbenzylidene)-4-methylbenzenesulfonohydrazide
• Synonyms: N′-(4-tert-butylbenzylidene)-4-methylbenzenesulfonohydrazide
• CAS NO: 65609-73-6
• Molecular Weight: 330.451
• Mol File: 65609-73-6.mol

Chemical Properties

• CAS DataBase Reference: N′-(4-tert-butylbenzylidene)-4-methylbenzenesulfonohydrazide(CAS DataBase Reference)
• NIST Chemistry Reference: N′-(4-tert-butylbenzylidene)-4-methylbenzenesulfonohydrazide(65609-73-6)
• EPA Substance Registry System: N′-(4-tert-butylbenzylidene)-4-methylbenzenesulfonohydrazide(65609-73-6)

Safety Data

• Hazardous Substances Data: 65609-73-6(Hazardous Substances Data)

Upstream product

• 939-97-9 4-tert-Butylbenzaldehyde 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 

Downstream Products

• 98-73-7 4-(1,1-dimethylethyl)benzoic acid 
• 1454769-95-9 (E)-1,3-dimethyl-3-(4'-tert-butylstyryl)indolin-2-one 
• 1606128-14-6 3-(4-(tert-butyl)phenyl)-5-chloro-1H-indazole 
• 1346143-36-9 9-[4-(tert-butyl)benzyl]phenanthrene 

Relevant articles and documents

Pd-Catalyzed Cascade Metallo-Ene Cyclization/Metallo-Carbene Coupling of Allenamides

A highly efficient palladium-catalyzed cascade metallo-ene/metallo-carbene coupling reaction was developed to produce 2,3-dihydropyrrole derivatives in high yields. In this transformation, two new Csp3?Csp2 and Csp2?Cspsu

Umpolung Difunctionalization of Carbonyls via Visible-Light Photoredox Catalytic Radical-Carbanion Relay

The combination of photoredox catalysis with the Wolff-Kishner (WK) reaction allows the difunctionalization of carbonyl groups by a radical-carbanion relay sequence (photo-Wolff-Kishner reaction). Photoredox initiated radical addition to N-sulfonylhydrazones yields α-functionalized carbanions following the WK-type mechanism. With sulfur-centered radicals, the carbanions are further functionalized by reaction with electrophiles including CO2 and aldehydes, whereas CF3 radical addition furnishes a wide range of gem-difluoroalkenes through β-fluoride elimination of the generated α-CF3 carbanions. More than 80 substrate examples demonstrate the broad applicability of this reaction sequence. A series of investigations including radical inhibition, deuterium labeling, fluorescence quenching, cyclic voltammetry, and control experiments support the proposed radical-carbanion relay mechanism.

Synthesis of 1 H-Pyrazol-5-yl-pyridin-2-yl-[1,2,4]triazinyl Soft-Lewis Basic Complexants via Metal and Oxidant Free [3 + 2] Dipolar Cycloaddition of Terminal Ethynyl Pyridines with Tosylhydrazides

Soft-Lewis basic complexants that facilitate chemoselective separation of the minor actinides from the lanthanides are critical to the closure of the nuclear fuel cycle. Complexants that modulate covalent orbital interactions with relevant metals of inter

Palladium-Catalyzed Intermolecular Carbene Insertion Prior to Intramolecular Heck Cyclization: Synthesis of 2-Arylidene-3-aryl-1-indanones

A domino process that converges the migratory insertion of carbene with a Heck reaction has been established as a versatile tool for the synthesis of 2-arylidene-3-aryl-1-indanones from very stable and easily accessible N-tosylhydrazones and 2′-iodochalco

Efficient synthesis of 1,5-disubstituted carbohydrazones using K 2CO3 as a carbonyl donor

A novel reaction that generates 1,5-disubstituted carbohydrazones via the carbonylation of tosylhydrazones has been developed. For the first time, the inexpensive, readily available, environmentally friendly, and nongaseous potassium carbonate is used as