656221-52-2

Basic information

• Product Name: 1-Cyclohexene-1-carboxamide,N-[2-(2-propenyloxy)phenyl]-(9CI)
• Synonyms: 1-Cyclohexene-1-carboxamide,N-[2-(2-propenyloxy)phenyl]-(9CI)
• CAS NO: 656221-52-2
• Molecular Formula: C₁₆H₁₉NO₂
• Molecular Weight: 257.32756
• Product Categories: AMIDE
• Mol File: 656221-52-2.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 452.0±45.0 °C(Predicted)
• Appearance: /
• Density: 1.126±0.06 g/cm3(Predicted)
• PKA: 15.08±0.70(Predicted)
• CAS DataBase Reference: 1-Cyclohexene-1-carboxamide,N-[2-(2-propenyloxy)phenyl]-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Cyclohexene-1-carboxamide,N-[2-(2-propenyloxy)phenyl]-(9CI)(656221-52-2)
• EPA Substance Registry System: 1-Cyclohexene-1-carboxamide,N-[2-(2-propenyloxy)phenyl]-(9CI)(656221-52-2)

Safety Data

• Hazardous Substances Data: 656221-52-2(Hazardous Substances Data)

Upstream product

• 36278-22-5 1-cyclohexenoyl chloride 
• 636-82-8 cyclohexene-1-carboxylic acid 

Downstream Products

• 656221-54-4 2-hydroxy-[4.5]-dec-7-en-8-yl-carbonyl-N-methylaniline 
• 656221-55-5 trifluoromethanesulfonyloxy-[4.5]-dec-7-en-8-yl-carbonyl-N-methylaniline 
• 656221-53-3 2-allyloxy-[4.5]-dec-7-en-8-yl-carbonyl-N-methylaniline 

Relevant articles and documents

Palladium complexes of phosphinamine ligands in the intramolecular asymmetric Heck reaction

The synthesis of two novel cyclisation substrates for the asymmetric intramolecular Heck reaction is reported. Their cyclisation, in addition to a known substrate for cis-decalin formation, were tested with palladium complexes of BINAP and heterobidentate oxazoline-containing ligands. In general BINAP provides a more active catalyst system for the range of substrates tested although excellent enantioselectivities of up to 85% were obtained with the P,N ligands studied. A trend was noted whereby the t-leucine-derived oxazoline ligands were more reactive and enantioselective than the valine-derived analogues. Similarly, the diphenylphosphinoferrocenyloxazoline ligands were more reactive and selective than the corresponding diphenylphosphinophenyloxazoline ligands.