656233-47-5

Usage

Uses

Given the provided materials, there are no specific applications listed for (11aR)-10,11,12,13-tetrahydro-N,N-bis[(1S)-1-phenylethyl]-Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-aMine. However, due to its unique structure and functional groups, it is likely that (11aR)-10,11,12,13-tetrahydro-N,N-bis[(1S)-1-phenylethyl]-Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-aMine could be explored for various applications in pharmaceutical or chemical research. Further research and testing would be necessary to determine its potential uses and benefits in specific industries or applications.

Upstream product

• 10024-74-5 (R,R)-N,N-bis-(1-phenylethyl)amine 
• 21003-56-5 (1S,1'S)-bis(1-phenylethyl)amine 
• 905984-16-9 lithium [R(R*,R*)]-(+)-bis(α-methylbenzyl)amide 
• 223137-87-9 2,2′,3,3′-tetrahydro-1,1′-spirobi[indene]-7,7′-diol 
• 223137-87-9 (R)-2,2',3,3'-tetrahydro-1,1'-spirobi[indene]-7,7'-diol 

Relevant academic research and scientific papers

Development of Axially Chiral Cyclo-Biaryldiol Ligands with Adjustable Dihedral Angles

A new type of axially chiral cyclo-[1,1′-biphenyl]-2,2′-diol (CYCNOL) ligands with adjustable dihedral angles have been developed by varying the bridge chain length. Eight-, nine- and ten-membered cyclo-ligands were prepared and evaluated by using two representative examples: enantioselective additions of diethylzinc to aldehydes and organometallic reagents to enones. The results revealed that the fine regulation of dihedral angles through variation of the bridge chain length was effective in the asymmetric synthesis.

Highly enantioselective copper-catalyzed conjugate addition of diethylzinc to enones using chiral spiro phosphoramidites as ligands

Novel monodentate chiral spiro phosphoramidite ligands have been readily synthesized in good yields from enantiomerically pure 1,1′-spirobiindane-7,7′-diol. The new ligands were highly efficient in the copper-catalyzed conjugate addition of Et2