656252-29-8

Upstream product

• 386703-34-0 5-[1-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-3-methoxy-5-methyl-phenyl]-meth-(Z)-ylidene]-6-methyl-heptan-2-one 
• 386703-32-8 3-[2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methoxy-5-methyl-benzyl]-2-methyl-hept-6-en-3-ol 
• 386703-33-9 tert-butyl-[2-(2-isopropyl-hexa-1,5-dienyl)-6-methoxy-4-methyl-benzyloxy]-dimethyl-silane 
• 386703-35-1 5-[2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methoxy-5-methyl-benzyl]-6-methyl-heptan-2-one 
• 656252-27-6 1-[2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methoxy-5-methyl-phenyl]-hex-5-en-2-ol 
• 386703-31-7 1-[2-(tert-butyl-dimethyl-silanyloxymethyl)-3-methoxy-5-methyl-phenyl]-hex-5-en-2-one 
• 656252-26-5 3-but-3-enyl-8-methoxy-6-methyl-isochroman-1-one 
• 10353-53-4 1,2-epoxy-5-hexene 

Downstream Products

• 656252-23-2 (E)-6-(2-Formyl-3-methoxy-5-methyl-benzyl)-3,7-dimethyl-oct-2-enoic acid methyl ester 

Relevant academic research and scientific papers

Total synthesis of hamigerans: Part 1. Development of synthetic technology for the construction of benzannulated polycyclic systems by the intramolecular trapping of photogenerated hydroxy-o-quinodimethanes and synthesis of key building blocks

A streamlined and general method for the construction of benzannulated systems such as I involves the intramolecular Diels - Alder reaction of photochemically generated hydroxy-o-quinodimethanes, for example, II. The method was optimized to set the stage