656831-07-1Relevant academic research and scientific papers
New Fischer Carbene Complexes of Rhodium(I): Preparation and 2-Cyclopentenone Ring Synthesis by Annelation to Alkynes
Barluenga, Jose,Vicente, Ruben,Lopez, Luis A.,Rubio, Eduardo,Tomas, Miguel,Alvarez-Rua, Carmen
, p. 470 - 471 (2004)
A new type of metal carbene complexes of group 9, specifically a cationic Fischer carbene of rhodium(I), has been synthesized from chromium carbene complexes via double transfer of carbene and CO ligands. These complexes reveal a different reactivity than other transition metal carbenes, including their chromium precursors, toward neutral and electron-poor alkynes, giving selectively polysubstituted cyclopentenones. Copyright
