65691-15-8Relevant academic research and scientific papers
Adamantanyl-substituted PEPPSI-type palladium(II) N-heterocyclic carbene complexes: synthesis and catalytic application for CH activation of substituted thiophenes
Glushkov, Vladimir A.,Denisov, Michail S.,Gorbunov, Aleksey A.,Myalitzin, Yurii A.,Dmitriev, Maksim V.,Slepukhin, Pavel A.
, p. 217 - 228 (2019)
[Figure not available: see fulltext.] Starting from 1-adamantanyl-3-imidazole, a number of new 1-adamantanyl-3-benzylimidazolium salts and corresponding unsymmetrically substituted Pd(II) PEPPSI-type complexes were prepared, including dichloride, dibromide, and diiodide. Single crystal X-ray crystallography confirmed solid state structures in six cases. The complexes reported in this work displayed moderate activities as precatalysts for CH activation/arylation reaction of substituted thiophenes.
A trisulfur radical anion (S3-) involved sulfur insertion reaction of 1,3-enynes: Sulfide sources control chemoselective synthesis of 2,3,5-trisubstituted thiophenes and 3-thienyl disulfides
Li, Jing-Hao,Huang, Qi,Rao, Weidong,Wang, Shun-Yi,Ji, Shun-Jun
supporting information, p. 7808 - 7811 (2019/07/08)
Cascade cyclization reactions of S3-in situ generated from S2- with 1,3-enynes for the chemoselective synthesis of 2,3,5-trisubstituted thiophenes and 3-thienyl disulfides controlled by sulfide salts are develop
Thiophenes useful in control of acarids
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, (2008/06/13)
Substituted thiophenes of the following formula, some of which are new compounds, are useful in controlling certain pests, particularly mites: STR1 wherein A, Y and Z are various substituents such as phenyl and substituted phenyl.
