65693-23-4Relevant academic research and scientific papers
Bu2SnIH-promoted proximal bond cleavage of methylenecyclopropanes and successive radical cyclization and/or Pd-catalyzed coupling reaction
Hayashi, Naoki,Hirokawa, Yusuke,Shibata, Ikuya,Yasuda, Makoto,Baba, Akio
, p. 2912 - 2913 (2008/09/20)
The unprecedented regioselective hydrostannation of methylenecyclopropanes to give vinyltins was achieved using dibutyliodotin hydride (Bu2SnIH), which could be applied to intramolecular radical cyclization. Copyright
Preparation of methylene-gem-difluorocyclopropanes and its reactivity as Michael Acceptor
Taguchi, Takeo,Kurishita, Masahito,Shibuya, Akira,Aso, Kifune
, p. 9497 - 9508 (2007/10/03)
Preparation of methylene-gem-difluorocyclopropanes 3 was achieved through the selenoxide elimination reaction derived from gem- difluorocyclopropylmethanols 1, while this method can not be applied to non- fluorinated cyclopropylmethanols. The methylene-gem-difluorocyclopropane 3 showed a high reactivity as a Michael acceptor in the reaction with thiol or amine.
