65693-77-8Relevant academic research and scientific papers
BENZOPHENANTHRIDINES. X. INVESTIGATION OF THE RODIONOV-SUVOROV SCHEME. REDUCTIVE ACETYLATION OF THE OXIMES OF 3-ETHOXYCARBONYL-SUBSTITUTED 2-PHENYLTETRAL-1-ONES WITH STANNOUS CHLORIDE IN ACETIC ANHYDRIDE
Maslennikova, L. V.,Sladkov, V. I.,Levina, I. I.,Kurkovskaya, L. N.,Suvorov, N. N.
, p. 2165 - 2170 (2007/10/02)
When treated with anhydrous stannous chloride in acetic anhydride, the oximes of benzyl phenyl ketone and 3-alkoxycarbonyl- and 3,3-dialkoxycarbonyl-2-phenyltetralones give a mixture of enamides and enimides.The direction of the reaction does not depend on the configuration of the oxime.It takes place in a more well-defined manner with the derivatives of 2-phenyltetralones used in the synthesis of benzophenanthridines by the Rodionov-Suvorov method.
