65725-25-9Relevant academic research and scientific papers
Oxymercuration-Demercuration of Allals: Novel Synthesis of 2,3-Unsaturated α-O-Glycosides
Mukhopadhyay, Aloka,Suryawanshi, S. N.,Bhakuni, D. S.
, p. 1009 - 1011 (2007/10/02)
Oxymercuration-demercuration of 4,6-O-benzylidene-3-(allylthioacetyl)-D-allal (1) in the presence of R-OH provides 2,3-unsaturated α-O-glycosides (2a-d) and the aldehydes (3a,b) in a stereospecific manner.
REACTION OF 4,6-O-BENZYLIDENE-3-O-MESYL-ALLAL WITH ALLYLIC GRIGNARD REAGENTS. HIGHLY REGIO- AND STEREOSELECTIVE PREPARATION OF 2,6-DISUBSTITUTED DIHYDROPYRAN RINGS
Ogihara, Takuo,Mitsunobu, Oyo
, p. 3505 - 3508 (2007/10/02)
The reaction of 4,6-O-benzylidene-1,2-dideoxy-3-O-mesyl-D-ribo-hex-1-enopyranose reacted with 2-propenylmagnesium chloride or 2-methyl-2-propenylmagnesium chloride to give 1,5-anhydro-4,6-O-benzylidene-2,3-dideoxy-1-C-prop-2-enyl- (or 2-methylprop-2-enyl)-β-D-erythro-hex-2-enitol in good yield.
