65748-25-6Relevant academic research and scientific papers
Regioselective 1,3-dipolar cycloaddition of nitrilimines to 2-methyl-2-vinyl oxirane
Yldrm, Muhammet,Dürüst, Yaar
experimental part, p. 3209 - 3215 (2011/05/30)
1,3-Dipolar cycloaddition of in situ generated C,N-diaryl nitrilimines to 2-methyl-2-vinyl oxirane gives rise to the regioselective formation of novel 5-(2-methyloxiranyl)-4,5-dihydropyrazole derivatives in moderate to good yields. The structures and ster
Synthesis of 1,3,4-thiadiazolines from 1,2-dithiole-3-thiones
Ogurtsov, Vladimir A.,Rakitin, Oleg A.,Rees, Charles W.,Smolentsev, Alexey A.
, p. 55 - 56 (2007/10/03)
The thiocarbonyl group of 4,5-dichloro-1,2-dithiole-3-thione reacts as a 1,3-dipolarophile towards diaryl nitrile imines by 1,3-dipolar cycloaddition followed by opening of the dithiole ring with loss of sulfur to give 5-methylene-1,3,4-thiadiazolines; th
REACTION DE DIARYLNITRILIMINES SUR DES 2-ARYLIDENE-TETRALIN-1-ONES SUBSTITUEES. INFLUENCE DES FACTEURS CONFORMATIONNELS SUR LA DIASTEREOCHIMIE DE LA REACTION
Kerbal, Abdelali,Tshiamala, Kabula,Vebrel, Joel,Laude, Bernard,Mercier, M.-F.
, p. 159 - 168 (2007/10/02)
Spiropyrazolines have been synthetized by 1,3-dipolar cycloaddition of some 2-arylidene-1-tetralones with diarylnitrilimines.It is shown that ring-closure reaction is regiospecific.The diastereoselectivity of the reaction is strongly dependent on the conf
The 1,3-dipolar cycloadditions of nitrile oxides and nitrile imines to alkyl dicyanoacetates
Neidlein, Richard,Sui, Zhihua
, p. 501 - 507 (2007/10/02)
The readily available alkyl dicyanoacetates 1 reacted with the 1,3-dipolar reagents arenecarbonitrile oxides 2′ and arenecarbonitrile imines 5′ to afford 1,2,4-oxadiazol and 1,2,4-triazol derivatives. The arenecarbonitrile oxides 2′ with electron-donating
Photochemistry of Diarylsubstituted 2H-Tetrazoles, XI and Sydnones. V. Flashphotolytic Investigations with 2,5-Diaryl-2H-tetrazoles and 3,4-Diarylsydnones. Absolute Rate Constants of Cycloadditionreactions of Diarylnitrile Imines to Dipolarophils
Leihkauf, P.,Lohse, V.,Csongar, Ch.,Tomaschewski, G.
, p. 789 - 798 (2007/10/02)
The flash photolysis of 2,5-Diaryl-2H-tetrazoles 1 and 3,4-Diarylsydnones 2 was investigated.The nitrile imines were detected spectroscopically as short living intermediates.Rate constants of the cycloaddition reaction of nitrile imines and dipolarophiles
Photochemistry of Diarylsubstituted 2H-Tetrazoles. II. The Influence of the Substituents on the Absorption Properties of Diarylsubstituted Nitrilimines
Csongar, Ch.,Leihkauf, P.,Lohse, V.,Tomaschewski, G.
, p. 96 - 102 (2007/10/02)
Irradation of 2,5-diaryl-2H-tetrazoles in an EPA-glass (ether: i-pentan: ethanol = 5:5:2) or in an i-pentan glass at 77-80 K with UV-light of wavelength 290 nm yields diarylnitrilimines by the extrusion of nitrogen.The photoreactions investigated show spe
