65774-75-6Relevant articles and documents
DNA cleavage by neocarzinostatin chromophore. Establishing the intermediacy of chromophore-derived cumulene and biradical species and their role in sequence-specific cleavage
Myers, Andrew G.,Cohen, Scott B.,Kwon, Byoung-Mog
, p. 1670 - 1682 (2007/10/02)
Experiments establishing the intermediacy of the cumulene 3 and the biradical 4 in the cleavage of double-stranded DNA by neocarzinostatin chromophore (1) and methyl thioglycolate (2) are described. It is shown that, in the presence of millimolar concentr