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65784-89-6

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65784-89-6 Usage

Molecular structure

Bicyclic ring system containing oxygen and nitrogen atoms, methoxy group, and two hydroxyl groups

Potential applications

Medicinal chemistry and drug development

Importance

Structural complexity and potential biological activity

Potential outcomes

New therapeutic agents or drug candidates with novel mechanisms of action and improved pharmacological properties

Check Digit Verification of cas no

The CAS Registry Mumber 65784-89-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,5,7,8 and 4 respectively; the second part has 2 digits, 8 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 65784-89:
(7*6)+(6*5)+(5*7)+(4*8)+(3*4)+(2*8)+(1*9)=176
176 % 10 = 6
So 65784-89-6 is a valid CAS Registry Number.

65784-89-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name 3-methoxy-2-oxa-6-azabicyclo[3.2.1]octane-4,8-diol

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:65784-89-6 SDS

65784-89-6Relevant articles and documents

SYNTHESIS OF THE INDOLIZIDINE ALKALOID SWAINSONINE FROM D-GLUCOSE

Ali, Mezher,Hough, Leslie,Richardson, Anthony C.

, p. 224 - 240 (2007/10/02)

Since the stereochemistry of the alkaloid exactly matches that of 3-amino-3-deoxy-D-mannose, he latter compound is an ideal chiron for the synthesis of the former.Selective tosylation of methyl 3-benzyloxycabonylamino-3-deoxy-α-D-mannopyranoside, followed by removal of the benzyloxycarbonyl group and cyclisation, afforded the 3,6-imine which was converted into its benzyloxycarbonyl derivative.Hydrolysis of the glycosidic group the afforded 3,6-benzyloxycarbolylimino-3,6-dideoxy-D-mannose.The attempted addition of a C2 unit at C-1 by the Wittig or the Wadsworth-Emmons-Horner reaction either failed to give the required product or was followed by Michael addition of one of the hydroxyl groups to the newly formed double-bond. 2,4,5-Tri-O-acetyl-3,6-benzyloxycarbonylimino-3,6-dideoxy-aldehydo-D-mannose was prepared via the diethyl dithioacetal and condensed with ethoxycarbonylmethylenetriphenylphosphorane to give the Wittig adduct in good yield, which, on catalytic reduction, underwent hydrogenation of the double bond, loss of the benzyloxycarbonyl group, and attack of the released amino group on either the terminal ethoxycarbonyl group or the 2-O-acetyl group to give a mixture of the required cyclic lactam and the N-acetyl derivative.Reduction of the lactam with the borane-dimethyl sulfide complex afforded swanisonine triacetate, from which the parent alkaloid was obtained.

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