65807-57-0Relevant articles and documents
Reactions of transition-metal nucleophiles with transition-metal efectrophiles. Reactions of acyliron, acylnickei, and cobalt carbonyl anions with (π-Allyl)palladium compieies
Hegedus, Louis S.,Tamura, Rui
, p. 1188 - 1194 (2008/10/08)
(π-Allyl)palladium chloride complexes react with anionic acyiiron tetracarbonyl complexes and anionic acylnickel carbonyl complexes to produce α,α- and β,γ-unsaturated ketones, resulting from acylation of the π-allyl ligand. A variety of π-allyl complexes and acylmetal complexes were studied. Pailadium(II) complexes, including (π-allyl)palladium halides, catalyzed the carbomethoxylation of allyl acetates by NaCo(CO)4. The key step in all of these reactions was thought to be nucleophilic attack of the anionic metal carbonyl complex on a (π-allyl)palladium species.
