65818-33-9

Basic information

• Product Name: 1-Propene, 1,2-bis(ethylthio)-, (Z)-
• CAS NO: 65818-33-9
• Molecular Formula: C7H14S2
• Molecular Weight: 162.32
• Mol File: 65818-33-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Propene, 1,2-bis(ethylthio)-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propene, 1,2-bis(ethylthio)-, (Z)-(65818-33-9)
• EPA Substance Registry System: 1-Propene, 1,2-bis(ethylthio)-, (Z)-(65818-33-9)

Safety Data

• Hazardous Substances Data: 65818-33-9(Hazardous Substances Data)

Upstream product

• 78-95-5 chloroacetone 
• 75-08-1 ethanethiol 

Relevant articles and documents

REACTION OF Α-CHLORO KETONES WITH THIOLS

The reaction of α-chloro ketones with ethane-, propane-, and butanethiols leads to the corresponding (alkylthio)alkenes.Noncyclic chloro ketones give a mixture of the cis and trans isomers of di(alkylthio)alkenes, while the reaction of α-chloropinacoline leads only to the cis isomers of the 1,2-di(alkylthio)-3,3-dimethyl-1-butene.The mechanism of the reaction of α-chloro ketones with thiols includes nucleophilic substitution of the chlorine with the formation of alkylthio ketones.The addition of a further molecule leads to the corresponding intermediate alkylthio a cohols, which are easily dehydrated to the final products under the acidic conditions.