65853-80-7Relevant academic research and scientific papers
Oxidative coupling rearrangement product based on tryptamine skeleton and preparation method and application thereof
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Paragraph 0019-0027, (2021/09/01)
The invention discloses an oxidative coupling rearrangement product based on a tryptamine skeleton and a preparation method and application thereof, wherein a corresponding dicarbonyl compound is obtained by oxidizing a color amine compound by using sodiu
Studies on the Syntheses of Heterocyclic Compounds. Part 876. The Chiral Total Synthesis of Brevianamide E and Deoxybrevianamide E
Kametani, Tetsuji,Kanaya, Naoaki,Ihara, Masataka
, p. 959 - 963 (2007/10/02)
The chiral total synthesis of brevianamide E (1) and deoxybrevianamide E (2) starting from L-proline is described.Condensation of 2-(1,1,dimethylallyl)-3-dimethylaminomethylindole (3) and (-)-methyl 1,4-dioxoperhydropyrrolopyrazine-3-carboxylate (7
Oxidative Cleavage Reaction of 3-Substituted Indoles Catalyzed by CuCl-Pyridine Complex under Oxygen
Tsuji, Jiro,Kezuka, Hiroaki,Takayanagi, Hiroshi,Yamamoto, Keiji
, p. 2369 - 2373 (2007/10/02)
Oxidative cleavage of 3-methylindole using a catalytic amount of copper (II) salts with added pyridine under an oxygen atmosphere was studied.Smooth cleavage of 3-methylindole took place to give 2-formamidoacetophenone in 73-80percent yield, whereas exclusive formation of a hydrate compound derived from 3,3'-dimethyl-3,3'-bi-3H-indole resulted under anaerobic conditions.Clean oxidative cleavage of N-acetyltryptamine, methyl 3-indolylacetate, and methyl 2-acetamido-3-(3-indolyl)propionate was also achieved, constituting a mimic of tryptophan-2,3-dioxygenase.
