65856-99-7

Upstream product

• 103851-05-4 (C₆Cl₄H)(((C₆H₅)2PCH₂)2)Pd(CH₂CHCHCH₃) 
• 56-23-5 tetrachloromethane 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 
• 63249-53-6 (C₆HCl₄)((C₆H₅)3P)Pd(CH₂CHCHCH₃) 
• 103836-55-1 (C₆F₅)((C₆H₅)3P)Pd(CH₂CHCHCH₃) 
• 103836-51-7 (C₆F₅)(((C₆H₅)2PCH₂)2)Pd(CH₂CHCHCH₃) 
• 62415-25-2 (C₆Cl₄H)(((C₆H₅)2PCH₂)2)Pd(CH₂CHCH₂) 

Downstream Products

• 90143-77-4 [Pd(C₆F₅)(dppe)(SCN)] 
• 212497-51-3 Pd(SC₆F₅)(C₆F₅)((C₆H₅)2PCH₂CH₂P(C₆H₅)2) 
• 212498-27-6 Pd(II) pentafluorophenyl(OSO₂CF₃) 1,2-bis(diphenylphosphino)ethane 

Relevant academic research and scientific papers

Reactions of η1-allyl complexes of palladium(II) with electrophiles. Molecular structure of a [2 + 3] cycloadduct of (η1-allyl)palladium with maleic anhydride

(η1-Allyl)arylpalladium complexes react with some electrophiles (HCl, Br2, NBS; NBS = N-bromo-succinimide) to give selective Pd-allyl bond cleavage (allylic substitution) with 1,3-transposition, while the corresponding (η3-allyl)arylpalladium analogues react with these electrophiles via selective Pd-Ar bond cleavage. The η1-allyl complexes also react with CCl4 and CHCl3 under very mild conditions to give good yields of CH2=CHCHR(CR′Cl2) (R = H, Me; R′ = Cl, H). Reactions of maleic anhydride with some of the above (η1-allyl)palladium complexes afford 1:1 adducts arising from formal [2 + 3] cycloaddition. The molecular structure of an adduct, PdCHCH2CHC(O)OC(O)CHCH2](C6F 5)((Z)-Ph2PCH=CHPPh2), has been determined by X-ray crystallography. Crystal data: triclinic, space group P1, a = 9.526 (3) A?, b = 14.218 (5) A?, c = 14.122 (5) A?, a = 70.47 (3)°, β = 96.48 (3)°, γ = 92.64 (3)°, and Z = 2. The palladium and the carbonyl substituents are located trans to each other with respect to the five-membered ring. Possible pathways to the cycloadduct are discussed in terms of this stereoselectivity.