658707-29-0Relevant academic research and scientific papers
TEMPO/NaIO4-SiO2: A catalytic oxidative rearrangement of tertiary allylic alcohols to β-substituted α,β-unsaturated ketones
Shibuya, Masatoshi,Tomizawa, Masaki,Iwabuchi, Yoshiharu
supporting information; scheme or table, p. 4715 - 4718 (2009/05/31)
(Chemical Equation Presented) The novel catalytic method for the oxidative rearrangement of tertiary allylic alcohols to β-substituted α,β-unsaturated ketones is described. TEMPO/NaIO4-SiO 2 causes facile and efficient oxidative rearrangement of various acyclic substrates as well as medium-sized and macrocyclic substrates.
