65898-71-7Relevant academic research and scientific papers
Palladium(0)-catalyzed reaction of cyclopropylidenecycloalkanes with carbon dioxide
Chen, Kai,Jiang, Min,Zhang, Zhen,Wei, Yin,Shi, Min
supporting information; experimental part, p. 7189 - 7193 (2012/01/19)
Cyclopropylidenecycloalkanes, which are highly strained methylenecyclopropane (MCPs) containing a cycloalkane moiety, react with carbon dioxide smoothly to give the corresponding five-membered lactone derivatives in moderate to good yields through a cyclo
Deracemization of quaternary stereocenters by Pd-catalyzed enantioconvergent decarboxylative allylation of racemic β-ketoesters
Mohr, Justin T.,Behenna, Douglas C.,Harned, Andrew M.,Stoltz, Brian M.
, p. 6924 - 6927 (2007/10/03)
(Chemical Equation Presented) Stereochemical alchemy! Racemic allyl β-ketoesters allow the regiocontrolled formation of enolates, where the same catalyst is intimately involved in both the stereoablative (C-C bond-breaking) and stereoselective (C-C bond-f
The enantioselective Tsuji allylation
Behenna, Douglas C.,Stoltz, Brian M.
, p. 15044 - 15045 (2007/10/03)
The first catalytic enantioselective examples of the Tsuji allylation using enol carbonates and enol silanes are described. The products possess a quaternary stereogenic center and are useful building blocks for synthetic chemistry. Copyright
Versatile Desilylative Cross-Coupling of Silyl Enol Ethers and Allylic Silanes via Oxovanadium-Induced Chemoselective One-Electron Oxidation
Hirao, Toshikazu,Fujii, Takashi,Ohshiro, Yoshiki
, p. 10207 - 10214 (2007/10/02)
The chemoselective cross-coupling of silyl enol ethers and allylic silanes to γ,δ-unsaturated ketones is achieved by the oxovanadium(V)-induced oxidative desilylation of the more readily oxidizable organosilicon compounds.
