65936-11-0

Basic information

• Product Name: propan-2-yl biphenyl-2-carboxylate
• CAS NO: 65936-11-0
• Molecular Formula: C₁₆H₁₆O₂
• Molecular Weight: 240.297
• Mol File: 65936-11-0.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 368.1°C at 760 mmHg
• Flash Point: 163.1°C
• Density: 1.063g/cm³
• Vapor Pressure: 1.3E-05mmHg at 25°C
• Refractive Index: 1.548
• CAS DataBase Reference: propan-2-yl biphenyl-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: propan-2-yl biphenyl-2-carboxylate(65936-11-0)
• EPA Substance Registry System: propan-2-yl biphenyl-2-carboxylate(65936-11-0)

Safety Data

• Hazardous Substances Data: 65936-11-0(Hazardous Substances Data)

Upstream product

• 939-48-0 isopropyl benzoate 
• 5123-13-7 5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane 
• 65935-91-3 2-Methanesulfinyl-benzoic acid isopropyl ester 
• 71-43-2 benzene 
• 67-63-0 isopropyl alcohol 
• 947-84-2 2-Biphenylcarboxylic acid 

Relevant articles and documents

Pronounced rate enhancements in condensation reactions attributed to the fluorous tag in modified Mukaiyama reagents

The observed rate enhancement for the condensation reaction between 2-phenyl benzoic acid and isopropanol mediated by fluorous Mukaiyama reagents is described. It is shown that Mukaiyama reagents bearing a fluorous tag increase the reaction rate considerably when compared to their non-fluorous tagged counterpart. Furthermore, it is observed that the longer the fluorous chain, the higher the activity of the Mukaiyama reagent.

A fluorous Mukaiyama coupling reagent for a concise condensation reaction: Utility of medium-fluorous strategy

The entire study of condensation reactions using various fluorous Mukaiyama reagents, including a novel medium-fluorous strategy, is described. A Mukaiyama reagent bearing a medium-fluorous content tag, between 40 and 60% fluorine by weight, was prepared and examined in ester and amide-forming condensation reactions. At the end of the reactions, the fluorous pyridone by-product was effectively separated from non-fluorous components by increasing the water content of the crude reaction mixture and subsequent filtration of the precipitate. It is also shown that Mukaiyama reagents bearing a fluorous tag increase the reaction rate considerably when compared to their non-fluorous tagged counterpart. Interestingly, it was observed that the longer the fluorous chain, the higher the activity of the Mukaiyama reagent.