65946-46-5Relevant academic research and scientific papers
Lithium perchlorate diethyl ether/methyl triflate catalyzed transfer of silicon from oxygen to carbon in silyl ketene (Thio) acetals
Heydari, Akbar,Alijanianzadeh, Reza
, p. 226 - 227 (2003)
Migration of a trimethylsilyl group from oxygen to the α-carbon (retro- [1,3]-Brook rearrangement) in silyl ketene acetals is catalyzed by LPDE/methyl triflate under mild conditions.
Direct C-C Bond Formation from Alkanes Using Ni-Photoredox Catalysis
Ackerman, Laura K. G.,Martinez Alvarado, Jesus I.,Doyle, Abigail G.
supporting information, p. 14059 - 14063 (2018/10/24)
A method for direct cross coupling between unactivated C(sp3)-H bonds and chloroformates has been accomplished via nickel and photoredox catalysis. A diverse range of feedstock chemicals, such as (a)cyclic alkanes and toluenes, along with late-stage intermediates, undergo intermolecular C-C bond formation to afford esters under mild conditions using only 3 equiv of the C-H partner. Site selectivity is predictable according to bond strength and polarity trends that are consistent with the intermediacy of a chlorine radical as the hydrogen atom-abstracting species.
