66017-06-9Relevant academic research and scientific papers
o-Quinonoid Compounds. Part 16. 1,5-Shift of Vinyl Groups in 1,3-Dimethylindenes; Product Studies and Migratory Aptitudes of Substituted Vinyl Groups
Field, Douglas J.,Jones, David W.
, p. 714 - 721 (2007/10/02)
Several 1-vinylindenes (1; X = substituent) undergo clean thermal rearrangement to 2-vinylindenes (2; X = Me, Ph, C6H4NO2-p, CHO, CO2Et, CN, CO2Ph, COPh, CONHMe, and COMe).Racemisation rates for the optically active indenes E-(1) provide migratory aptitud
