66035-59-4Relevant academic research and scientific papers
A new series of organoboranes. III. Some reactions of 1,2-dicarbaclovododecaborane(12) and its derivatives
Heying,Ager Jr.,Clark,Alexander,Papetti,Reid,Trotz
, p. 1097 - 1105 (1963)
The general participation of carborane and its derivatives in standard organic chemical transformations has been established. Reactions of carborane and some functionally substituted derivatives are described. Differences in the reactivity of the hydrogen atoms attached to carbon atoms of carborane from those attached to the boron atoms have been demonstrated.
Carboranes. II. The preparation of 1- and 1,2-substituted carboranes
Fein, Marvin M.,Grafstein, Daniel,Paustian, John E.,Bobinski, Jack,Lichstein, Bernard M.,Mayes, Nathan,Schwartz, Nelson N.,Cohen, Murray S.
, p. 1115 - 1119 (2008/10/08)
The broad applicability o the conversion of mono- and disubstituted acetylenes to carboranes by treatment with decaborane and Lewis bases is demonstrated. The resultant carboranes may then be treated as typically organic, covalent products and, by usual s
Carboranes. III. Reactions of the carboranes
Grafstein, Daniel,Bobinski, Jack,Dvorak, Joseph,Smith, Harry,Schwartz, Nelson,Cohen, Murray S.,Fein, Marvin M.
, p. 1120 - 1125 (2008/10/08)
The reactions of the carboranyl polyhedron and its influence on the chemistry of organofunctional substituents were investigated. Convenient laboratory syntheses for carborane, 1-methylcarborane, and some functional derivatives were developed. An unusual rearrangement in a Grignard reagent was observed. Metalation, animation, solvolytic degradation, and other reactions of these novel compounds were studied.
