66114-62-3Relevant academic research and scientific papers
Transition metal complexes of 3-cyano- and 3-nitroformazans
Gilroy, Joe B.,Patrick, Brian O.,McDonald, Robert,Hicks, Robin G.
, p. 1287 - 1294 (2008)
The synthesis and characterization of six transition metal complexes of 3-cyano- and 3-nitroformazans are described. Three different formazans were reacted with nickel(II) to produce complexes with bidentate formazan ligands. Mononuclear NiL2 (L = deprotonated formazan) or binuclear hydroxo-bridged (LNi)2(μ-OH)2 species were produced depending on the steric bulk on the formazan N-aromatic substituents. 1,5-Bis(2-methoxyphenyl)-3-cyanoformazan acts as a tetradentate monoanionic ligand in a copper(II) complex, whereas the analogous 1,5-bis(2-hydroxyphenyl)- 3-cyanoformazan binds as a trianion in a tetradentate manner to Fe(III) and Co(III). Crystal structures - the first examples of metal complexes of cyano- or nitroformazans - as well as the electronic spectra of the complexes are discussed in relation to each other as well as that of the uncoordinated formazans.
