66128-99-2Relevant academic research and scientific papers
Palladium-Catalyzed Tandem Oxidative Arylation/Olefination of Aromatic Tethered Alkenes/Alkynes
Gao, Yang,Gao, Yinglan,Wu, Wanqing,Jiang, Huanfeng,Yang, Xiaobo,Liu, Wenbo,Li, Chao-Jun
supporting information, p. 793 - 797 (2017/02/05)
We describe herein a palladium-catalyzed tandem oxidative arylation/olefination reaction of aromatic tethered alkenes/alkynes for the synthesis of dihydrobenzofurans and 2 H-chromene derivatives. This reaction features a 1,2-difunctionalization of C?C π-bond with two C?H bonds using O2as terminal oxidant at room temperature. The products obtained are valuable synthons and important scaffolds in biological agents and natural products.
Pd-Catalyzed regioselective hydroesterification of 2-allylphenols to seven-membered lactones without external CO gas
Chang, Wenju,Li, Jingfu,Ren, Wenlong,Shi, Yian
supporting information, p. 3047 - 3052 (2016/03/19)
Effective Pd-catalyzed regioselective hydroesterification of 2-allylphenols with phenyl formate is described. A variety of seven-membered lactones can be obtained in good yields under mild conditions without the use of toxic CO gas.
