6617-49-8Relevant articles and documents
A new approach for bio-jet fuel generation from palm oil and limonene in the absence of hydrogen
Zhang, Jingjing,Zhao, Chen
supporting information, p. 17249 - 17252 (2015/12/08)
The traditional methodology includes a carbon-chain shortening strategy to produce bio-jet fuel from lipids via a two-stage process with hydrogen. Here, we propose a new solution using a carbon-chain filling strategy to convert C10 terpene and lipids to jet fuel ranged hydrocarbons with aromatic hydrocarbon ingredients in the absence of hydrogen.
Synthetic approaches towards trans-calamenene and related molecular modelling studies
Bhonsle, Jayendra B.
, p. 372 - 379 (2007/10/03)
Synthesis of cadalene (12), γ-calacorene (13), epizonarene (9A)-zonarene (9B) and (+/-)-calamenene (4) from epibicycloquiphellandrene (6), which was prepared from 7(S)-isopropyl-10(R)-methyl-1(S)-4-oxobicyclodec-5-ene (5) in quantitative yields, is reported.Molecular modelling studies of all the compounds are also reported.
STABLE CARBOCATIONS FROM TERPENOIDS.IX. MOLECULAR REARRANGEMENTS OF α-MUROLENE AND α-COPAENE WITH THE FORMATION OF TRICYCLIC COMPOUNDS
Polovinka, M. P.,Mamatyuk, V. I.,Korchagina, D. V.,Sal'nikov, G. E.,Gatilov, Yu. V.,et al.
, p. 863 - 882 (2007/10/02)
Tricyclic compounds were obtained from α-murolene and α-copaene in superacidic media, and this agrees with the scheme for the biogenetic transformations of these substances.It was found that the temperature at which the stable cations are generated from α-murolene has an effect on the ratio of the paths leading to the formation of the bi- and tricyclic ions.The prediction of the most probable paths for the transformation of α-copaene agrees with the actually observed transformation of the stable ions generated from this substance.The preferred direction in the ske letal rearrangements of the investigated compounds depends on the nature of the acid medium.