662143-15-9

Basic information

• Product Name: Cyclopropanemethanol, 2-[(triphenylmethoxy)methyl]-
• CAS NO: 662143-15-9
• Molecular Formula: C24H24O2
• Molecular Weight: 344.453
• Mol File: 662143-15-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclopropanemethanol, 2-[(triphenylmethoxy)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropanemethanol, 2-[(triphenylmethoxy)methyl]-(662143-15-9)
• EPA Substance Registry System: Cyclopropanemethanol, 2-[(triphenylmethoxy)methyl]-(662143-15-9)

Safety Data

• Hazardous Substances Data: 662143-15-9(Hazardous Substances Data)

Upstream product

• 75-11-6 diiodomethane 
• 126027-87-0 (Ζ)-4-(triphenylmethoxy)-2-buten-1-ol 

Relevant articles and documents

Catalytic enantioselective cyclopropanation of allylic alcohols using recyclable fluorous disulfonamide ligand

Cyclopropanation of allylic alcohols with Et2Zn and CH2I2 in the presence of a catalytic amount of fluorous disulfonamide 3 afforded the corresponding cyclopropylmethanols in 69-96% yield with 49-83% ee. The fluorous ligand 3 was readily recovered from the reaction mixture by the fluorous solid-phase extraction (FSPE) and could be reused without a significant loss of the catalytic activity and enantioselectivity.