66221-08-7Relevant academic research and scientific papers
Photochemistry of Cyclopropene Derivatives. Synthesis of the Tricyclo2,6>hexane Ring System via a Photosensitized Cycloaddition Reaction
Padwa, Albert,Blacklock, Thomas J.,Cordova, Diana M.,Loza, Roman
, p. 7202 - 7210 (2007/10/02)
The photosensitized triplet reactions of several 3-allyl-substituted diphenylcyclopropenes have been studied.The triplet-sensitized irradiations gave diphenyl-substituted tricyclo2,6>hexanes in good yield by means of a novel intramolecu
Thermal Isomerization of Allyl-Substituted Cyclopropenes. An Example of a Nonsynchronous Cope Rearrangement
Padwa, Albert,Blacklock, Thomas J.
, p. 2797 - 2806 (2007/10/02)
The thermal Cope rearrangement of a number of allyl-substituted cyclopropenes has been studied in mechanistic detail.Thermolysis of 1,2-diphenyl-3-allyl-3-methylcyclopropene produced an equilibrium mixture of recovered starting material (35percent), 1,3-d
Photochemistry of Cyclopropene Derivatives. Formation and Intramolecular Trapping Reactions of Vinylcarbenes
Padwa, Albert,Blacklock, Thomas J.,Loza, Roman,Polniaszek, Richard
, p. 2181 - 2189 (2007/10/02)
The intramolecular photocycloaddition reactions of a number of 3-allyl-substituted diphenylcyclopropenes have been studied.Photodimerization occured when 1,2-diphenyl-3-allylcyclopropene was irradiated in benzene.The photodimerization reaction was shown t
